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单词 Madelung Constants
释义

Madelung Constants

The quantities obtained from cubic, hexagonal, etc., Lattice Sums, evaluated at , are calledMadelung constants. For cubic Lattice Sums, they are expressible in closed form for Even indices,

(1)
(2)

is given by Benson's Formula,


(3)

where the prime indicates that summation over (0, 0, 0) is excluded. is sometimes called ``the'' Madelung constant,corresponds to the Madelung constant for a 3-D NaCl crystal, and is numerically equal to .


For hexagonal Lattice Sum, is expressible in closed form as

(4)

See also Benson's Formula, Lattice Sum


References

Borwein, J. M. and Borwein, P. B. Pi & the AGM: A Study in Analytic Number Theory and Computational Complexity. New York: Wiley, 1987.

Buhler, J. and Wagon, S. ``Secrets of the Madelung Constant.'' Mathematica in Education and Research 5, 49-55, Spring 1996.

Crandall, R. E. and Buhler, J. P. ``Elementary Function Expansions for Madelung Constants.'' J. Phys. Ser. A: Math. and Gen. 20, 5497-5510, 1987.

Finch, S. ``Favorite Mathematical Constants.'' http://www.mathsoft.com/asolve/constant/mdlung/mdlung.html


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